Download Catalysis by transition metal sulphides : from molecular by Raybaud PDF

By Raybaud

ISBN-10: 1680153358

ISBN-13: 9781680153354

ISBN-10: 2710809915

ISBN-13: 9782710809913

The major software of transition steel sulphides as reliable catalysts is for construction of fresh fuels in petroleum refineries. some of the feedstocks to be processed all comprise kind of sulphur, integrated in hugely reliable heteroaromatic molecules. that allows you to meet the stringent requisites imposed all over the world these days on transportation fuels to minimize their environmental influence, catalytic hydroprocessing is still crucial. during this approach, sulphur is got rid of as H2S following the response among molecular hydrogen and the heteroaromatics. This publication goals to supply an entire, entire, and up to date survey of the sphere that would be beneficial to a person concerned; the scholar beginning a study venture, the tutorial researcher, or the refinery engineer will deepen their wisdom at the features of the catalytic technique. Thirty-seven experts from IFP Energies nouvelles, CNRS, and French universities have contributed, reporting a special synthesis of the final fifteen years of research.

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Extra info for Catalysis by transition metal sulphides : from molecular theory to industrial application

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Today 130, p 149. Gandubert A, Legens C, Guillaume D, Rebours S and Payen E (2007) X-ray Photoelectron Spectroscopy Surface Quantification of Sulfided CoMoP Catalysts – Relation between Activity and Promoted Sites – Part I: Influence of the Co/Mo ratio. Oil and Gas Sci. and Technology – Rev. IFP 62, p 79. Garreau FB, Toulhoat H, Kasztelan S and Paulus R (1986) Low-temperature Synthesis of Mixed NiMo Sulfides: Structural, Textural and Catalytic Properties. Polyhedron 5, p 211. Grillo ME and Sautet P (2000) Density Functional Study of the Structural and Electronic Properties of RuS2(111): II.

17) is obtained at lower p(H2S)/p(H2). 40) and minimises the number of mixed sites. , 1989], the working NiMoS crystallites are believed to combine edge structures thus allowing the presence of mixed Ni-Mo edge sites. , 2004]. 25 illustrates the comparison between simulated STM images for the CoMoS nano-particles and the experimental ones. It appears that the substitution of Mo by Co or Ni at the edges triggers an increase in the electronic density close to the Fermi level localised on the basal S-atoms interacting with the promoter at the edge.

174, p 130. Clausen BS and Topsøe H (1989) In situ Studies of Catalysts by XAFS and Mössbauer Spectroscopy. Hyperfine Interact. 47, p 203. Clausen BS, Topsøe H, Candia R, Villadsen J, Lengeler B, Als-Nielsen J and Christensen F (1981) Extended x-ray Absorption Fine Structure Study of the Cobalt-molybdenum Hydrodesulfurization Catalysts. J. Phys. Chem. 85, p 3868. Curie MP (1885) Sur la formation des cristaux et sur les constantes capillaires de leurs différentes faces. Bull. Soc. Min. France 8, p 145.

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Catalysis by transition metal sulphides : from molecular theory to industrial application by Raybaud

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